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By default, the Xiaomi smartphone asks us which SIM card to use for outgoing calls. To disable the question, we can also set a SIM card as the default.

Android 11 | MIUI 12.0
Step 1: Tap on  Settings
Step 2: Tap on  SIM cards & mobile networks
Step 3: Choose  SIM 1 / 2  or  Select SIM card to dial
  1. Tap on Settings
  2. Tap on SIM cards & mobile networks
  3. Choose SIM 1 / 2 or Select SIM card to dial
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Xiaomi Instructions