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We can assign a SIM card to the saved contacts on the Xiaomi smartphone to make outgoing calls only and not always make a manual choice.

Android 11 | MIUI 12.0
Step 1: Tap on  Contacts
Step 2: Choose a  Contact
Step 3: Open the  Menu
Step 4: Tap on  Set calling SIM
Step 5: Choose a  SIM card   (Dual SIM)  and tap  OK
  1. Tap on Contacts
  2. Choose a Contact
  3. Open the Menu
  4. Tap on Set calling SIM
  5. Choose a SIM card (Dual SIM) and tap OK
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Xiaomi Instructions