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Dark Mode can be automatically switched on and off on the Samsung device, either between sunset and sunrise or according to a user-defined schedule.

Android 11 | One UI 3.0
Step 1: Tap on  Settings
Step 2: Tap on  Display
Step 3: Tap on  Dark mode settings
Step 4: Enable  Turn on as scheduled
Step 5: Choose  Sunset to sunrise  or  Custom schedule
Step 6: Set the  Start/End time
  1. Tap on Settings
  2. Tap on Display
  3. Tap on Dark mode settings
  4. Enable Turn on as scheduled
  5. Choose Sunset to sunrise or Custom schedule
  6. Set the Start/End time
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Samsung Instructions