Night mode on Samsung devices can also be automatically switched on or off using a schedule, and in addition to a user-defined schedule with a fixed time, night mode can also be switched on from sunset to sunrise.

Android 10 (One UI 2.0)
Step 1:  Open the  Settings
Step 2:  Tap on  Display
Step 3:  Tap on  Night mode
Step 4:  Enable or disable  Turn on as scheduled
  1. Open the Settings
  2. Tap on Display
  3. Tap on Night mode
  4. Enable or disable Turn on as scheduled

Samsung Instructions
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